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Journal Article

Design of extended surface-supported chiral metal-organic arrays comprising mononuclear iron centers

MPS-Authors
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Dmitriev,  A.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Spillmann,  H.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Lingenfelder,  M.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Lin,  N.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Barth,  J. V.
Former Research Groups, Max Planck Institute for Solid State Research, Max Planck Society;
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Kern,  K.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Dmitriev, A., Spillmann, H., Lingenfelder, M., Lin, N., Barth, J. V., & Kern, K. (2004). Design of extended surface-supported chiral metal-organic arrays comprising mononuclear iron centers. Langmuir, 20(12), 4799-4801.


Cite as: https://hdl.handle.net/21.11116/0000-000E-FED0-9
Abstract
A design strategy for fabricating a surface-supported chiral
metal-organic system comprising a regular arrangement of mononuclear
iron centers and nanocavities is presented. By sequential deposition of
1,2,4-benzenetricarboxylic acid (tmla) molecules and iron atoms on a
Cu(100) surface under ultrahigh vacuum conditions, chiral square-planar
Fe(tmla)(4) metal-organic complexes are generated, which order in
extended homochiral arrays. Structure formation and envisioned
functionality of such metal-organic architectures are discussed.