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Journal Article

Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60-

MPS-Authors
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Hönnerscheid,  A.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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van Wüllen,  L.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Dinnebier,  R. E.
Scientific Facility X-Ray Diffraction (Robert E. Dinnebier), Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Hönnerscheid, A., van Wüllen, L., Dinnebier, R. E., Jansen, M., Rahmer, J., & Mehring, M. (2004). Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60-. Physical Chemistry Chemical Physics, 6(9), 2454-2460.


Cite as: https://hdl.handle.net/21.11116/0000-000E-FE84-F
Abstract
We report a detailed study of the structure, dynamics and electronic
structure of the new fulleride [Cr(C9H12)(2)]-(+)-C-60(-). Using a
variety of characterization tools including EPR, NMR, SQUID magnetic
measurements and high resolution X-ray powder diffraction a spin
pairing of the C-60(-) spins with decreasing temperatures could be
observed. Contrary to the observed phase transition of first order in
the related compound [Cr(C6H9)(2)]C-+(60)- the phase transition
observed in the title compound is of higher order.