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Journal Article

Growth and characterization of BPO4 single crystals

MPS-Authors
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Schmidt,  M.
Research Group Organic Electronics (Hagen Klauk), Max Planck Institute for Solid State Research, Max Planck Society;

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Loa,  I.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280715

Zhang,  L.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Huang,  Y. X.
Department Physical Chemistry of Solids (Joachim Maier), Max Planck Institute for Solid State Research, Max Planck Society;

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Schwarz,  U.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Schmidt, M., Ewald, B., Prots, Y., Cardoso-Gil, R., Armbruster, M., Loa, I., et al. (2004). Growth and characterization of BPO4 single crystals. Zeitschrift für anorganische und allgemeine Chemie, 630(5), 655-662.


Cite as: https://hdl.handle.net/21.11116/0000-000E-FE5E-C
Abstract
Single crystals of BPO4 were grown by chemical transport reactions with
PCl5 using a gradient from 1073 K to 973 K as well as with solvothermal
syntheses in the temperature range between 413 K and 523 K using water,
ethanol or 2-propanol as polar protic solvents. The atomic arrangement
of BPO4 was reinvestigated by means of single crystal X-ray diffraction
data and confirmed the earlier findings with significantly smaller
standard deviations. Thermogravimetric investigations of powdered
samples which show no extra lines in X-ray diffraction diagrams
revealed weight decrements which are attributed to water losses. The
presence of protonated borate and phosphate species in a number of
X-ray pure solvothermally grown BPO4 samples is evidenced by infrared
spectroscopy.