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Infrared optical properties of the spin-1/2 quantum magnet TiOCl

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Kovaleva,  N. N.
Department Solid State Spectroscopy (Bernhard Keimer), Max Planck Institute for Solid State Research, Max Planck Society;

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Lemmens,  P.
Department Solid State Spectroscopy (Bernhard Keimer), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Caimi, G., Degiorgi, L., Kovaleva, N. N., Lemmens, P., & Chou, F. C. (2004). Infrared optical properties of the spin-1/2 quantum magnet TiOCl. Physical Review B, 69(12): 125108.


Cite as: https://hdl.handle.net/21.11116/0000-000E-FE92-F
Abstract
We report results on the electrodynamic response of TiOCl, a
low-dimensional spin-1/2 quantum magnet that shows a spin gap formation
for T<T-c1 = 67 K. The Fano-like shape of a few selected, infrared
active phonons suggests an interaction between lattice vibrations and a
continuum of low-frequency (spin) excitations. The temperature
dependence of the phonon mode parameters extends over a broad
temperature range well above T-c1, indicating the presence of an
extended fluctuation regime. In the temperature interval between 200 K
and T-c1, there is a progressive dimensionality crossover (from two to
one), as well as a spectral weight shift from low towards high
frequencies. This allows us to identify a characteristic energy scale
of about 430 K, ascribed to a pseudo-spin-gap.</textarea>

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