Steering molecular organization and host-guest interactions using 
two-dimensional nanoporous coordination systems

Stepanow, S.; Lingenfelder, M.; Dmitriev, A.; Spillmann, H.; Delvigne, E.; Lin, N.; Deng, X. B.; Cai, C. Z.; Barth, J. V.; Kern, K.

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Steering molecular organization and host-guest interactions using two-dimensional nanoporous coordination systems

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Stepanow, S.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Lingenfelder, M.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Dmitriev, A.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280550

Spillmann, H.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Lin, N.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Barth, J. V.
Former Research Groups, Max Planck Institute for Solid State Research, Max Planck Society;
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Kern, K.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Stepanow, S., Lingenfelder, M., Dmitriev, A., Spillmann, H., Delvigne, E., Lin, N., et al. (2004). Steering molecular organization and host-guest interactions using two-dimensional nanoporous coordination systems. Nature Materials, 3(4), 229-233.

Cite as: https://hdl.handle.net/21.11116/0000-000E-F8B5-E

Abstract

Metal - organic coordination networks (MOCNs) have attracted wide
interest because they provide a novel route towards porous materials
that may find applications in molecular recognition, catalysis, gas
storage and separation(1,2). The so-called rational design principle -
synthesis of materials with predictable structures and properties - has
been explored using appropriate organic molecular linkers connecting to
metal nodes to control pore size and functionality of open coordination
networks(3-9). Here we demonstrate the fabrication of surface-supported
MOCNs comprising tailored pore sizes and chemical functionality by the
modular assembly of polytopic organic carboxylate linker molecules and
iron atoms on a Cu(100) surface under ultra-high-vacuum conditions.
These arrays provide versatile templates for the handling and
organization of functional species at the nanoscale, as is demonstrated
by their use to accommodate C-60 guest molecules.
Temperature-controlled studies reveal, at the single-molecule level,
how pore size and chemical functionality determine the host - guest
interactions.