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Journal Article

Synthesis and structure of sodium tetraoxo nitrido molybdate, Na5MoO4N

MPS-Authors
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Arumugam,  N.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Peters,  E.-M.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280091

Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Arumugam, N., Peters, E.-M., & Jansen, M. (2004). Synthesis and structure of sodium tetraoxo nitrido molybdate, Na5MoO4N. Zeitschrift für Naturforschung B, 59(3), 274-276.


Cite as: https://hdl.handle.net/21.11116/0000-000E-F725-2
Abstract
The new oxynitride of molybdenum, Na5MoO4N was prepared from
stoichiometric mixtures of the starting materials MoO2, Na2O2 and NaN3
which were heated in a special regime up to 500 degreesC, and cooled
down slowly. Its crystal structure was solved and refined from single
crystal data (orthorhombic, Cmcm, a = 991.1(2), b = 574.3(1), c =
1067.7(2) pm, R-1 = 0.0153, wR(2) = 0.0427). The structure consists of
isolated [MoO4N](5-) rectangular pyramids which are separated by Na+
cations. This compound is structurally related to Na5WO4N which
crystallizes in space group Cmc2(1).