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Triapua-1κO,2κO,3κO-hexakis-μ-chloroacetato-1:2κ4O:O';2:3κ4O:O';1:3κ4O:O'-μ3-oxo-triiron(III) nitrate trihydrate

MPS-Authors
/persons/resource/persons280425

Ren,  X.-M.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280355

Okudera,  H.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280185

Kremer,  R. K.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Ren, X.-M., Okudera, H., & Kremer, R. K. (2004). Triapua-1κO,2κO,3κO-hexakis-μ-chloroacetato-1:2κ4O:O';2:3κ4O:O';1:3κ4O:O'-μ3-oxo-triiron(III) nitrate trihydrate. Acta Crystallographica E, 60, M14-M16.


Cite as: https://hdl.handle.net/21.11116/0000-000E-F777-6
Abstract
The title compound, [Fe3O(C2H2ClO2)(6)(H2O)(3)]NO3.3H(2)O, contains an
Fe-III trimeric cation in which the three Fe-III ions are at the
corners of a slightly distorted triangle with an O atom in the centre.
Two monochloroacetate ligands bridge each pair of Fe-III ions and a
water molecule coordinates each Fe-III ion at the apex, opposite to the
central O atom. Hence, the Fe-III ions are surrounded by distorted
oxygen octahedra. The distances between the Fe-III ions and the central
O atoms are considerably shorter than those between the Fe-III ions and
the other coordinated O atoms. The trimeric cations form a
three-dimensional connected network via hydrogen-bonding interactions
to extra-cluster water molecules and nitrate anions.