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Journal Article

Twinned α-LiRb2(CF3SO3)3

MPS-Authors
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Pompetzki,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Friese,  K.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280091

Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Pompetzki, M., Friese, K., & Jansen, M. (2003). Twinned α-LiRb2(CF3SO3)3. Acta Crystallographica C, 59, I117-I119.


Cite as: https://hdl.handle.net/21.11116/0000-000E-E883-8
Abstract
The investigated crystal of alpha-LiRb2(CF3SO3)(3) [lithium dirubidium
tris(trifluoromethanesulfonate)] was a twin, with the twin matrix given
by ((1) over bar 00/010/001). The structure consists of channel-like
patterns built up of lipophilic CF3 groups pointing towards each other.
The polar interstices are occupied by cations. One Rb atom is
coordinated by O atoms in the form of a distorted square antiprism,
while the coordination around the second Rb atom is best described as a
distorted pentagonal plane, with one O atom and one F atom situated
above and an additional F atom below this plane. The O atoms around the
Li atom form a strongly distorted tetrahedron.