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The Structure of Twinned Ag4Mn3O8, a Novel Octahedral Framework with a Topology Related to the Archetype Cubic {10,3} Net

MPS-Authors
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Ahlert,  S.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Friese,  K.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280091

Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Ahlert, S., Friese, K., & Jansen, M. (2002). The Structure of Twinned Ag4Mn3O8, a Novel Octahedral Framework with a Topology Related to the Archetype Cubic {10,3} Net. Zeitschrift für anorganische und allgemeine Chemie, 628(7), 1525-1531.


Cite as: https://hdl.handle.net/21.11116/0000-000E-EE5F-D
Abstract
Preparative exploration of the system Ag-Mn-O under an elevated
oxygen pressure yielded so far unknown Ag4Mn3O8. Single crystal
X-ray investigations have revealed a trigonal crystal system,
space group P3(1)21 with lattice parameters a 12.5919(1) and c
= 15.4978(1) Angstrom. Due to fourfold twinning a large cubic
unit cell with a 26 A is simulated. The structure, which was
refined as a fourfold twin, is composed of MnO6 octahedra which
are connected via common edges to a complex framework. The
topology of this framework is closely related to the archetype
cubic, 10,3 If net. In the cavities of the framework the Ag+
ions are incorporated.