English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Stabilization of a diamagnetic ScIBr molecule in a sandwich-like structure

MPS-Authors
/persons/resource/persons280091

Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Neculai, A. M., Neculai, D., Roesky, H. W., Magull, J., Baldus, M., Andronesi, O., et al. (2002). Stabilization of a diamagnetic ScIBr molecule in a sandwich-like structure. Organometallics, 21(13), 2590-2592.


Cite as: https://hdl.handle.net/21.11116/0000-000E-E8ED-2
Abstract
Reaction of a new beta-diketiminato derivative of scandium,
LScBr2 (L = Et2NCH2CH2NC(Me)CHC-(Me)NCH2CH2NEt2), with
(C3H5)MgBr gave the unexpected scandium complex (LMgBr)(2)ScBr
(1), whose structure was established by X-ray analysis, liquid
and solid-state NMR, EPR, UV-vis, and magnetic measurements.
Correlation of all results leads to the conclusion that the
formal oxidation state of scandium in this complex is one
(Sc(I)) having no unpaired electrons.