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Journal Article

The cluster azides M2[Nb6Cl12(N3)6]·(H2O)4-x (M = Ca, Sr, Ba)

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Reckeweg,  O.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Simon,  A.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Reckeweg, O., Meyer, H. J., & Simon, A. (2002). The cluster azides M2[Nb6Cl12(N3)6]·(H2O)4-x (M = Ca, Sr, Ba). Zeitschrift für anorganische und allgemeine Chemie, 628(5), 920-922.


Cite as: https://hdl.handle.net/21.11116/0000-000E-E849-B
Abstract
The isotypic cluster compounds M-2[Nb6Cl12(N-3)(6)] . (H2O)(4-
x) (M = Ca (1), M = Sr (2) and M = Ba (3)) have been
synthesized by the reaction of an aequeous solution of Nb6Cl14
with M(N-3)(2), 1, 2 and 3 crystallize in the space group Fd(3)
over bar (No. 227) with the lattice constants a = 1990.03(23),
2015.60(12) and 2043,64(11)pm, respectively. All compounds
contain isolated 16e(-) clusters whose terminal positions are
all occupied by orientationally disordered azide ligands.