X-ray and Raman investigations on cyanides of mono- and divalent metals and 
synthesis, crystal structure and Raman spectrum of Tl5(CO3)2CN

Reckeweg, O.; Simon, A.

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X-ray and Raman investigations on cyanides of mono- and divalent metals and synthesis, crystal structure and Raman spectrum of Tl₅(CO₃)₂CN

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Reckeweg, O.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Simon, A.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Reckeweg, O., & Simon, A. (2002). X-ray and Raman investigations on cyanides of mono- and divalent metals and synthesis, crystal structure and Raman spectrum of Tl₅(CO₃)₂CN. Zeitschrift für Naturforschung B, 57(8), 895-900.

Cite as: https://hdl.handle.net/21.11116/0000-000E-E839-D

Abstract

Pseudobinary cyanides of monovalent and divalent metals were
synthesized, and X-ray and Raman data of the cyanides were
measured. Single crystal X-ray structure analyses were
performed on Zn(CN)(2) (Pn (3) over barm (No. 224), a =
591.32(7) pm), Hg(CN)(2) (I (4) over bar 2d (No. 122), a =
969.22(14) and c = 890,15(18) pm.) and for the first time on
AgCN (I (4) over bar 2d (No. 166), a = 600.58(8) and c =
526.28(11) pm). The data are compared with literature data. The
reaction of TlF and NaCN in 25% aqueous ammonia solution in air
led to Tl-5(CO3)(2)(CN) which was characterized by X-ray (Cmca
(No. 64), 1468.1(3), 1171.6(2) and 1266.0(3) pm) and Raman
spectroscopy.