The bis(maleonitriledithiolato)zincate(II) complex of the monoprotonated 
4,4'-bipyridine cation

Xu, H.; Xie, J. L.; Ren, X.-M.; Chen, Y. C.

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The bis(maleonitriledithiolato)zincate(II) complex of the monoprotonated 4,4'-bipyridine cation

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Ren, X.-M.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Xu, H., Xie, J. L., Ren, X.-M., & Chen, Y. C. (2002). The bis(maleonitriledithiolato)zincate(II) complex of the monoprotonated 4,4'-bipyridine cation. Acta Crystallographica E, 58, M750-M752.

Cite as: https://hdl.handle.net/21.11116/0000-000E-EE1D-7

Abstract

In the title salt, (C10H9N2)(2) [Zn(C4N2S2)(2)].C2H3N or [4,4'-
bipyH][Zn(mnt)(2)].C2H3N, where mnt(2-) denotes
maleonitriledithiolate and 4,4'-bipyH is monoprotonated 4,4'-
bipyridine, the Zn-II ion is tetrahedrally surrounded by four S
atoms of two mnt(2-) ligands. The counter-cations, 4,4'-
bipyH(+), form one-dimensional chains through strong
(pyridine)N- H...N(pyridine) hydrogen-bonding interactions.
Anions and cations stack in alternating layers which are nearly
parallel to the bc plane of the crystallographic unit cell.