Crystal structure of a rigid ferrocene-based macrocycle from high-resolution 
X-ray powder diffraction

Dinnebier, R. E.; Ding, L.; Ma, K. B.; Neumann, M. A.; Tanpipat, N.; Leusen, F. J. J.; Stephens, P. W.; Wagner, M.

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Crystal structure of a rigid ferrocene-based macrocycle from high-resolution X-ray powder diffraction

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Dinnebier, R. E.
Scientific Facility X-Ray Diffraction (Robert E. Dinnebier), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Dinnebier, R. E., Ding, L., Ma, K. B., Neumann, M. A., Tanpipat, N., Leusen, F. J. J., et al. (2001). Crystal structure of a rigid ferrocene-based macrocycle from high-resolution X-ray powder diffraction. Organometallics, 20(26), 5642-5647.

Cite as: https://hdl.handle.net/21.11116/0000-000E-EFDF-B

Abstract

A macrocycle, 6, has been synthesized in high yield from 2,5-
di(pyrazol-1-yl)hydroquinone and 1,1'-fc[B(Me)NMe2](2) {fc =
Fe(C5H4)(2)}. The molecule incorporates two redox-active 1,1'-
ferrocenylene units in its backbone and contains four chiral
boron centers, each of them possessing the same configuration.
It is demonstrated that crystal structures of organometallics
of moderate complexity can be solved from high-resolution X-ray
powder diffraction patterns, once the connectivity between the
functional groups is known.