Infrared spectroscopy of gas-phase zirconium oxide clusters

von Helden, Gert; Kirilyuk, Andrei; van Heijnsbergen, Deniz; Sartakov, Boris; Duncan, Michael A.; Meijer, Gerard

doi:/10.1016/S0301-0104(00)00267-6

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Infrared spectroscopy of gas-phase zirconium oxide clusters

MPS-Authors

There are no MPG-Authors in the publication available

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

von Helden, G., Kirilyuk, A., van Heijnsbergen, D., Sartakov, B., Duncan, M. A., & Meijer, G. (2000). Infrared spectroscopy of gas-phase zirconium oxide clusters. Chemical Physics, 262(1), 31-39. doi:/10.1016/S0301-0104(00)00267-6.

Cite as: https://hdl.handle.net/21.11116/0000-000B-6552-7

Abstract

Gas-phase zirconium oxide clusters are resonantly excited using IR radiation from a free electron laser. At sufficiently large excitation fluences, clusters with a composition Zr_nO_2n−1 are observed to thermally emit electrons. Scanning the IR wavelength while monitoring the ion yield gives IR spectra of the clusters. For all clusters, resonances are observed between 600 and 700 cm⁻¹ and the spectra are almost independent of cluster size.