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Pulsed ENDOR Studies at 95 GHz of the Triplet State of 13C60

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Citation

van den Berg, G. J. B., van den Heuvel, D. J., Poluektov, O. G., Holleman, I., Meijer, G., & Groenen, E. J. J. (1998). Pulsed ENDOR Studies at 95 GHz of the Triplet State of 13C60. Journal of Magnetic Resonance, 131(1), 39-45. doi:10.1006/jmre.1997.1343.


Cite as: https://hdl.handle.net/21.11116/0000-000B-6682-F
Abstract
Fully13C-enriched C60has been investigated by pulsed electron-nuclear double-resonance (ENDOR) spectroscopy at W-band frequency at 1.2 K. For molecular C60the ENDOR spectra reflect the distortion of the molecule upon triplet excitation, and the fine-structure parameter<em>D</em>is found to be negative. For a single crystal of C60the ENDOR spectra characterize the triplet excitation as delocalized over a pair of neighboring C60molecules.