Rotational order in CO-intercalated C60 crystals

van Smaalen, Sander; Dinnebier, Robert; Holleman, Iwan; von Helden, Gert; Meijer, Gerard

doi:10.1103/PhysRevB.57.6321

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Rotational order in CO-intercalated C₆₀ crystals

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van Smaalen, S., Dinnebier, R., Holleman, I., von Helden, G., & Meijer, G. (1998). Rotational order in CO-intercalated C₆₀ crystals. Physical Review B, 57(11), 6321-6324. doi:10.1103/PhysRevB.57.6321.

Cite as: https://hdl.handle.net/21.11116/0000-000C-1550-2

Abstract

The structure of (CO)_xC₆₀ (x=0.67) has been determined by x-ray powder diffraction at 25 K. CO is found distributed over six equivalent orientations on the octahedral sites of the cubic close-packed structure of C₆₀. The C₆₀ molecules are orientationally ordered in almost exclusively the major orientation. Evidence is presented for a weak electrostatic interaction between C₆₀ and CO.