A demonstration of the Franck—Condon principle upon ionization

Boogaarts, Maarten G.H.; Hinnen, Paul C.; Meijer, Gerard

doi:10.1016/0009-2614(94)00479-X

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A demonstration of the Franck—Condon principle upon ionization

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Boogaarts, M. G., Hinnen, P. C., & Meijer, G. (1994). A demonstration of the Franck—Condon principle upon ionization. Chemical Physics Letters, 223(5-6), 537-540. doi:10.1016/0009-2614(94)00479-X.

Cite as: https://hdl.handle.net/21.11116/0000-000C-081C-D

Abstract

Vibrationally resolved ionization probabilities have been recorded for laser-desorbed jet-cooled diphenylamine via the mass analyzed threshold ionization (MATI) technique. The observed MATI spectra from selected laser-prepared vibrational levels in the first electronically excited singlet state of DPA are a clear demonstration of the Franck—Condon principle upon ionization. The shape of the vibrational wavefunction in the intermediate electronic state is seen directly reflected in the spectra.