Vibrational Raman and infrared spectra of chromatographically separated C60 and 
C70 fullerene clusters

Bethune, Donald S.; Meijer, Gerard; Tang, Wade C.; Rosen, Hal J.; Golden, William G.; Seki, Hajime; Brown, Charles A.; de Vries, Mattanjah S.

doi:10.1016/0009-2614(91)90312-W

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Vibrational Raman and infrared spectra of chromatographically separated C₆₀ and C₇₀ fullerene clusters

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引用

Bethune, D. S., Meijer, G., Tang, W. C., Rosen, H. J., Golden, W. G., Seki, H., Brown, C. A., & de Vries, M. S. (1991). Vibrational Raman and infrared spectra of chromatographically separated C₆₀ and C₇₀ fullerene clusters. Chemical Physics Letters, 179(1-2), 181-186. doi:10.1016/0009-2614(91)90312-W.

引用: https://hdl.handle.net/21.11116/0000-000C-0704-8

要旨

We report vibrational Raman and infrared spectra for chemically separated C₆₀ and C₇₀ fullerenes. Thin film samples were prepared by subliming the chromatographically separated species onto appropriate substrates. The C₆₀ Raman spectrum shows eight clear lines and two weaker ones. If C₆₀ in fact that has the proposed buckminsterfullerene structure (as is strongly indicated by recent experiments), the present Raman measurements together with the four observed IR frequencies give a complete set of Raman and infrared active fundamental frequencies for this molecule. A comparison of this set with the calculated spectrum for buckminsterfullerene shows satisfactory agreement.