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Journal Article

Meerwein-type Bromoarylation with Arylthianthrenium Salts

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Cai,  Yuan
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ritter,  Tobias
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Cai, Y., & Ritter, T. (2022). Meerwein-type Bromoarylation with Arylthianthrenium Salts. Angewandte Chemie, International Edition, 61(47): e202209882. doi:10.1002/anie.202209882.


Cite as: https://hdl.handle.net/21.11116/0000-000B-9B90-3
Abstract
Herein, we report a photocatalyzed Meerwein-type bromoarylation of alkenes with stable arylthianthrenium salts, formed by site-selective C−H thianthrenation. This protocol can be applied to late-stage functionalization of a variety of biomolecules that are difficult to access by other aryl coupling reagents. Halogen introduction allows for a variety of follow-up transformations, affording numerous biologically active skeletons.