Precise tuning of interlayer electronic coupling in layered conductive 
metal-organic frameworks

Lu, Yang; Zhang, Yingying; Yang, Chi-Yuan; Revuelta, Sergio; Qi, Haoyuan; Huang, Chuanhui; Jin, Wenlong; Li, Zichao; Vega-Mayoral, Victor; Liu, Yannan; Huang, Xing; Pohl, Darius; Polozij, Miroslav; Zhou, Shengqiang; Canovas, Enrique; Heine, Thomas; Fabiano, Simone; Feng, Xinliang; Dong, Renhao

doi:10.1038/s41467-022-34820-6

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks

MPS-Authors

/persons/resource/persons47863

Feng, Xinliang
Department of Synthetic Materials and Functional Devices (SMFD), Max Planck Institute of Microstructure Physics, Max Planck Society;

External Resource

https://doi.org/10.1038/s41467-022-34820-6
(出版社版)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

s41467-022-34820-6.pdf
(出版社版), 3MB

付随資料 (公開)

There is no public supplementary material available

引用

Lu, Y., Zhang, Y., Yang, C.-Y., Revuelta, S., Qi, H., Huang, C., Jin, W., Li, Z., Vega-Mayoral, V., Liu, Y., Huang, X., Pohl, D., Polozij, M., Zhou, S., Canovas, E., Heine, T., Fabiano, S., Feng, X., & Dong, R. (2022). Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks. Nature Communications, 13(1):. doi:10.1038/s41467-022-34820-6.

引用: https://hdl.handle.net/21.11116/0000-000C-3F94-7

要旨

Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have attracted increasing interests for (opto)-electronics and spintronics. They generally consist of van der Waals stacked layers and exhibit layer-depended electronic properties. While considerable efforts have been made to regulate the charge transport within a layer, precise control of electronic coupling between layers has not yet been achieved. Herein, we report a strategy to precisely tune interlayer charge transport in 2D c-MOFs via side-chain induced control of the layer spacing. We design hexaiminotriindole ligands allowing programmed functionalization with tailored alkyl chains (HATI_CX, X = 1,3,4; X refers to the carbon numbers of the alkyl chains) for the synthesis of semiconducting Ni₃(HATI_CX)₂. The layer spacing of these MOFs can be precisely varied from 3.40 to 3.70 Å, leading to widened band gap, suppressed carrier mobilities, and significant improvement of the Seebeck coefficient. With this demonstration, we further achieve a record-high thermoelectric power factor of 68 ± 3 nW m⁻¹ K⁻² in Ni3(HATI_C3)₂, superior to the reported holes-dominated MOFs.