English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  DetailsSummary

Released
Journal Article

The First Alkaline-Earth Azidoaurate(III), Ba[Au(N3)4]2 ⋅ 4 H2O

MPS-Authors
/persons/resource/persons126806

Prots,  Yurii
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126668

Jach,  Franziska
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126657

Höhn,  Peter
Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Subaşı, Y., Tekin, E. S., Prots, Y., Jach, F., Somer, M., Afyon, S., et al. (2022). The First Alkaline-Earth Azidoaurate(III), Ba[Au(N3)4]2 ⋅ 4 H2O. Chemistry – A European Journal, 29(11): e202203501, pp. 1-6. doi:10.1002/chem.202203501.


Cite as: https://hdl.handle.net/21.11116/0000-000C-AC45-5
Abstract
Transparent, dark orange Ba[Au(N3)4]2 ⋅ 4 H2O was synthesized by reaction of Ba(N3)2 and AuCl3 or HAuCl4 in aqueous solution. The novel barium tetraazidoaurate(III) tetrahydrate crystallizes in the monoclinic space group Cc (no. 9) with a=1813.68(17) pm, b=1737.95(11) pm, c=682.04(8) pm and β=108.849(4)°. The predominant structural features of Ba[Au(N3)4]2 ⋅ 4 H2O are two crystallographically independent discrete anions [Au(N3)4]− with gold in a tetragonal planar coordination by nitrogen. Vibrational spectra show good agreement with those of other azidoaurates(III). Upon drying, this salt was shown to be a highly explosive material. © 2022 The Authors. Chemistry