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Abstract

Aims: The aim of this study is to measure the vertical distribution of HCN on Titan's stratosphere using ground-based submillimetre observations acquired quasi-simultaneously with the Herschel ones. This allows us to perform a consistency check between space and ground-based observations and to build a reference mean HCN vertical profile in Titan's stratosphere.
Methods: Using APEX and IRAM 30-m, we obtained the spectral emission of HCN (4-3) and (3-2) lines. Observations were reduced with GILDAS-CLASS. We applied a line-by-line radiative transfer code to calculate the synthetic spectra of HCN, and a retrieval algorithm based on optimal estimation to retrieve the temperature and HCN vertical distributions. We used the standard deviation-based metric to quantify the dispersion between the ground-based and Herschel HCN profiles and the mean one.
Results: Our derived HCN abundance profiles are consistent with an increase from 40 ppb at ~100 km to 4 ppm at ~200 km, which is an altitude region where the HCN signatures are sensitive. We also demonstrate that the retrieved HCN distribution is sensitive to the data information and is restricted to Titan's stratosphere. The HCN obtained from APEX data is less accurate than the one from IRAM data because of the poorer data quality, and covers a narrower altitude range. Comparisons between our results and the values from Herschel show similar abundance distributions, with maximum differences of 2.5 ppm ranging between 100 and 300 km in the vertical range. These comparisons also allow us to inter-validate both data sets and indicate reliable and consistent measurements. The inferred abundances are also consistent with the vertical distribution in previous observational studies, with the profiles from ALMA, Cassini/CIRS, and SMA (the latest ones below ~230 km). Our HCN profile is also comparable to photochemical models by <xref ref-type="bibr" rid="R21">Krasnopolsky (2014)</xref> and <xref ref-type="bibr" rid="R56">Vuitton et al. (2019)</xref> below 230 km and consistent with that of <xref ref-type="bibr" rid="R25">Loison et al. (2015)</xref> above 250 km. However, it appears to show large differences with respect to the estimates by <xref ref-type="bibr" rid="R25">Loison et al. (2015)</xref>, <xref ref-type="bibr" rid="R7">Dobrijevic & Loison (2018)</xref>, and <xref ref-type="bibr" rid="R27">Lora et al. (2018)</xref> below 170 km, and by <xref ref-type="bibr" rid="R7">Dobrijevic & Loison (2018)</xref> and <xref ref-type="bibr" rid="R27">Lora et al. (2018)</xref> above 400 km, although they are similar in shape. We conclude that these particular photochemical models need improvement. <P />Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.