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Journal Article

Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols

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Han,  Jung Tae
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Zhou,  Hui
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Han, J. T., Zhou, H., & List, B. (2023). Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols. Synlett, 34(20), 2393-2395. doi:10.1055/a-2100-1575.


Cite as: https://hdl.handle.net/21.11116/0000-000D-56F9-A
Abstract
We report a Brønsted acid catalyzed enantioselective silylation of biaryl diols with an allylsilane as silicon source. This process enables facile access to enantioenriched biaryl silyl ethers with an axial stereogenicity. A control experiment supports a mechanism proceeding by desymmetrization followed by kinetic resolution.