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Electronic structure of a Pt–Ge surface alloy

MPS-Authors
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Brillo,  Jürgen
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Kuhlenbeck,  Helmut       
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Freund,  Hans-Joachim       
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Fukutani, K., Murata, Y., Brillo, J., Kuhlenbeck, H., Freund, H.-J., & Taguchi, M. (2000). Electronic structure of a Pt–Ge surface alloy. Surface Science, 464(2-3), 48-56. doi:10.1016/S0039-6028(00)00711-1.


Cite as: https://hdl.handle.net/21.11116/0000-000D-903E-B
Abstract
The structural and electronic properties of a Pt(111)-Ge surface alloy are studied by scanning tunneling microscope and angle-resolved photoemission spectroscopy. The electronic band structure in the Γ-L direction was measured and compared with that of Pt(111). The crystal field parameters of 10Dq and ξ were evaluated to be 1.77 eV and 0.73 eV respectively. Alloying with Ge was found to reduce 10Dq and enhance ξ compared with pure Pt(111).