L-Cysteine Nitrates

Giester, G.; Ghazaryan, V. V.; Minkov, V. S.; Boldyreva, E. V.; Petrosyan, A. M.

doi:10.1134/S0022476623050104

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

L-Cysteine Nitrates

MPS-Authors

/persons/resource/persons203187

Minkov, V. S.
High Pressure Group, Max Planck Institute for Chemistry, Max Planck Society;

External Resource

https://link.springer.com/content/pdf/10.1134/S0022476623050104.pdf
(出版社版)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

There is no public supplementary material available

引用

Giester, G., Ghazaryan, V. V., Minkov, V. S., Boldyreva, E. V., & Petrosyan, A. M. (2023). L-Cysteine Nitrates. Journal of Structural Chemistry, 64(5), 917-931. doi:10.1134/S0022476623050104.

引用: https://hdl.handle.net/21.11116/0000-000D-8C31-E

要旨

The formation of salts in the L-cysteine–HNO3–H2O system was studied yielding three representatives as single crystals: anhydrous L-cysteinium nitrate (L-CysH)NO3 (I) and two new salts (L-CysH⋯L-Cys)NO3 (II) and (L-CysH⋯L-Cys)NO3∙0.5H2O (III) with the dimeric (L-CysH⋯L-Cys) cation. (I), (II) and (III) crystallize in space groups P212121, P21 and I2, respectively. Dimeric cations in (II) and (III) were formed by very short O–H⋯O hydrogen bonds with R(O⋯O) distances of 2.440(2) Å and 2.4352(17) Å, respectively. Infrared and Raman spectra of (I–III) were registered and discussed in relation to crystal structures. Characteristics of dimeric cations are compared with those in the previously obtained compounds of L-CysH(L-CysH⋯L-Cys)F(F⋯HF), (L-CysH⋯L-Cys)Cl, (L-CysH⋯L-Cys)Br and (L-CysH⋯L-Cys)I·0.5H2O.