Selective oxidation of alcohols using carbon nitride photocatalysts

Savateev, Aleksandr

doi:10.1002/9783527837991.ch3

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Selective oxidation of alcohols using carbon nitride photocatalysts

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Savateev, Aleksandr
Aleksandr Savateev, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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引用

Savateev, A. (2023). Selective oxidation of alcohols using carbon nitride photocatalysts. In X., Wang, M., Anpo, & X., Fu (Eds.), UV-visible photocatalysis for clean energy production and pollution remediation (pp. 27-40). Weinheim: Wiley-VCH GmbH. doi:10.1002/9783527837991.ch3.

引用: https://hdl.handle.net/21.11116/0000-000D-9288-4

要旨

The oxidation of alcohols mediated by semiconductor materials was one of the first organic photocatalytic reactions reported as early as the 1960s. Today, it is one of the most studied reactions in photocatalysis. The chapter summarizes a reaction mechanism of alcohol oxidation with O 2 mediated by carbon nitride photocatalysts. Selectivity toward carbonyl compounds and strategies adopted in carbon nitride research to improve selectivity are discussed. These strategies include performing the reaction in flow, the substitution of O 2 with other oxidants, such as S 8 , and employing hydrogen-evolving cocatalysts or photo-chargeable carbon nitrides to enable selective dehydrogenation of primary alcohols.