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Journal Article

Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene

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Mato,  Mauro
Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Takahashi,  Fumiya
Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Leutzsch,  Markus
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Cornella,  Josep
Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Mato, M., Bruzzese, P. C., Takahashi, F., Leutzsch, M., Reijerse, E. J., Schnegg, A., et al. (2023). Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene. Journal of the American Chemical Society, 145(34), 18742-18747. doi:10.1021/jacs.3c06651.


Cite as: https://hdl.handle.net/21.11116/0000-000D-A962-6
Abstract
The oxidative addition of aryl electrophiles is a fundamental organometallic reaction widely applied in the field of transition metal chemistry and catalysis. However, the analogous version based on main group elements still remains largely underexplored. Here, we report the ability of a well-defined organobismuth(I) complex to undergo formal oxidative addition with a wide range of aryl electrophiles. The process is facilitated by the reactivity of both the ground and excited states of N,C,N-bismuthinidenes upon absorption of low-energy red light.