Photodesorption of NO from Ni(100)-O

Budde, F.; Hamza, A. V.; Ferm, P.; Ertl, Gerhard; Weide, D.; Andresen, P.; Freund, Hans-Joachim

doi:10.1103/PhysRevLett.60.1518

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Photodesorption of NO from Ni(100)-O

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Budde, F.
Fritz Haber Institute, Max Planck Society;

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Hamza, A. V.
Fritz Haber Institute, Max Planck Society;

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Ferm, P.
Fritz Haber Institute, Max Planck Society;

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Ertl, Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Budde, F., Hamza, A. V., Ferm, P., Ertl, G., Weide, D., Andresen, P., et al. (1988). Photodesorption of NO from Ni(100)-O. Physical Review Letters, 60(15), 1518-1521. doi:10.1103/PhysRevLett.60.1518.

Cite as: https://hdl.handle.net/21.11116/0000-000E-715C-C

Abstract

Fully state-resolved analysis of NO molecules desorbed from an oxygen-covered Ni(100) surface by uv radiation (λ=193 nm) yields the operation of two desorption channels, thermal and nonthermal, via electronic excitation. The latter fraction exhibits as a particular feature pronounced spin-orbit selectivity at low rotational quantum numbers.