English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Core ionization of nitrosobenzene-dimer compounds: phenazon-di-N-oxide

MPS-Authors
There are no MPG-Authors in the publication available
External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Sjögren, B., Freund, H.-J., Salaneck, W., & Bigelow, R. (1987). Core ionization of nitrosobenzene-dimer compounds: phenazon-di-N-oxide. Chemical Physics, 118(1), 101-112. doi:10.1016/0301-0104(87)85039-5.


Cite as: https://hdl.handle.net/21.11116/0000-000E-44A1-F
Abstract
The C 1s, N 1s and O 1s XPS spectra of soli d phenazon-di-N-oxide (PADNO) are presented in order to further elucidate the effects of intermolecular interactions in molecular solids on the dynamics of the core-ionization process. PADNO can be considered a model compound for an intramolecular cis nitrosobenzene dimer. The observed strong N 1s and O 1s shake-up intensity attenuations in going from the nitrosobenzene monomer to PADNO are discussed in detail based on the results of CNDO/S CI equivalent core calculations. The theoretical core-hole spectral functions are in excellent agreement with experiment. It is shown that the calculated shake-up intensities are strongly on electron correlation.