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Journal Article

Core ionization of nitrosobenzene-dimer compounds: phenazon-di-N-oxide

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Citation

Sjögren, B., Freund, H.-J., Salaneck, W., & Bigelow, R. (1987). Core ionization of nitrosobenzene-dimer compounds: phenazon-di-N-oxide. Chemical Physics, 118(1), 101-112. doi:10.1016/0301-0104(87)85039-5.


Cite as: https://hdl.handle.net/21.11116/0000-000E-44A1-F
Abstract
The C 1s, N 1s and O 1s XPS spectra of soli d phenazon-di-N-oxide (PADNO) are presented in order to further elucidate the effects of intermolecular interactions in molecular solids on the dynamics of the core-ionization process. PADNO can be considered a model compound for an intramolecular cis nitrosobenzene dimer. The observed strong N 1s and O 1s shake-up intensity attenuations in going from the nitrosobenzene monomer to PADNO are discussed in detail based on the results of CNDO/S CI equivalent core calculations. The theoretical core-hole spectral functions are in excellent agreement with experiment. It is shown that the calculated shake-up intensities are strongly on electron correlation.