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A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

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Kazin,  P.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;
Scientific Facility X-Ray Diffraction (Robert E. Dinnebier), Max Planck Institute for Solid State Research, Max Planck Society;

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Dinnebier,  R. E.
Scientific Facility X-Ray Diffraction (Robert E. Dinnebier), Max Planck Institute for Solid State Research, Max Planck Society;

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Kremer,  R. K.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Kazin, P., Zykin, M., Trusov, L., Eliseev, A., Magdysyuk, O., Dinnebier, R. E., et al. (2017). A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation. Chemical Communications, 53(39), 5416-5419.


Cite as: https://hdl.handle.net/21.11116/0000-000E-D496-9
Abstract
An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U-eff of up to 387 cm(-1), which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).