Synergistic silver storage in the composite RbAg4I5:graphite: Thermodynamics 
and kinetics

Chen, C.-C.; Maier, J.

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Synergistic silver storage in the composite RbAg₄I₅:graphite: Thermodynamics and kinetics

MPS-Authors

/persons/resource/persons217129

Maier, J.
Department Physical Chemistry of Solids (Joachim Maier), Max Planck Institute for Solid State Research, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Chen, C.-C., & Maier, J. (2017). Synergistic silver storage in the composite RbAg₄I₅:graphite: Thermodynamics and kinetics. Solid State Ionics, 312, 97-105.

Cite as: https://hdl.handle.net/21.11116/0000-000E-D2CC-F

Abstract

The thermodynamics and kinetics of silver stoichiometry change in RbAg4I5:graphite composites briefly reported in a previous contribution are treated in detail. The stoichiometric variations occurring at the interface are achieved electrochemically and chemically. In samples that are not deliberately compacted samples, Stranski-Krastanov wetting of RbAg4I5 on carbon enables measurement of heterogeneous ambipolar Ag diffusion along the interface. If samples are deliberated compacted, the interfacial storage occurs through supercapacitive charging through the bulk path. The application of composites as electrodes in supercapacitor or battery mode underscores the very fast kinetics.