Synthesis, crystal structure and Raman spectrum of Ba7[BO3]3Br(O1.33F1.33)

Reckeweg, O.; Schulz, A.; DiSalvo, F.

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Synthesis, crystal structure and Raman spectrum of Ba₇[BO₃]₃Br(O_1.33F_1.33)

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Reckeweg, O.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Schulz, A.
Miscellaneous, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Reckeweg, O., Schulz, A., & DiSalvo, F. (2017). Synthesis, crystal structure and Raman spectrum of Ba₇[BO₃]₃Br(O_1.33F_1.33). Zeitschrift für Naturforschung B, 72(3), 193-197.

Cite as: https://hdl.handle.net/21.11116/0000-000E-D2C8-3

Abstract

In addition to amorphous material and Ba-7[BO3](4-x) F2-3x, air and moisture sensitive single crystals of Ba-7[BO3](3)Br(O-1.33 F-1.33) were formed from H3BO3, Ba(OH)(2), BaF2 and BaBr2 . 2 H2O in alumina crucibles open to the atmosphere at 1300 K for 13 h. Ba-7[BO3](3)Br(O1.33F1.33) crystallizes in the hexagonal space group P6(3)mc (no. 186, Z = 2) with the lattice parameters a = 1118.1(2) and c = 723.93(13) pm. The Raman spectrum of the title compounds was also acquired and is compared to literature data.