α-RbO3, a Low Temperature Polymorph of Rubidium Ozonide

Sans, A.; Nuss, H.; Mohitkar, S.; Jansen, M.

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

α-RbO₃, a Low Temperature Polymorph of Rubidium Ozonide

MPS-Authors

/persons/resource/persons280349

Nuss, H.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280091

Jansen, M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Sans, A., Nuss, H., Mohitkar, S., & Jansen, M. (2017). α-RbO₃, a Low Temperature Polymorph of Rubidium Ozonide. Zeitschrift für anorganische und allgemeine Chemie, 643(5), 357-359.

Cite as: https://hdl.handle.net/21.11116/0000-000E-CFA8-C

Abstract

Applying the known procedure for synthesis of alkali metal ozonides, just at a lower temperature, has yielded a new polymorph of rubidium ozonide, -RbO3 [P2(1); a = 436.3(2), b = 595.3(3), c = 548.7(3) pm, = 99.680(7), R = 0.0400, 1184 reflections]. Like previously reported -RbO3, the basic structural arrangement of anions and cations corresponds to the CsCl type of structure, however, the mutual orientation of the ozonide ions is different, in as much as one of the two terminal oxygen atoms is pointing to the adjacent bridging oxygen atom, forming a chain running along the b axis.