Trapping Reactive Intermediates by Mechanochemistry: Elusive Aryl 
N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents

Štrukil, V.; Gracin, D.; Magdysyuk, O. V.; Dinnebier, R. E.; Friščić, T.

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Trapping Reactive Intermediates by Mechanochemistry: Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents

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Dinnebier, R. E.
Scientific Facility X-Ray Diffraction (Robert E. Dinnebier), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Štrukil, V., Gracin, D., Magdysyuk, O. V., Dinnebier, R. E., & Friščić, T. (2015). Trapping Reactive Intermediates by Mechanochemistry: Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents. Angewandte Chemie International Edition, 54(29), 8440-8443.

Cite as: https://hdl.handle.net/21.11116/0000-000E-CB92-8

Abstract

Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.