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Journal Article

Cs3(O3)2(O2)•NH3: the First Mixed Alkali Metal Ozonide Superoxide

MPS-Authors
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Nuss,  H.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Nuss, H., & Jansen, M. (2012). Cs3(O3)2(O2)•NH3: the First Mixed Alkali Metal Ozonide Superoxide. Zeitschrift für anorganische und allgemeine Chemie, 638(3-4), 501-504.


Cite as: https://hdl.handle.net/21.11116/0000-000E-C409-B
Abstract
Cs3(O3)2(O2)center dot NH3 was prepared by the reaction of CsO3 and CsO2, in the presence of traces of NH4Cl, in liquid ammonia. It is the first example of a mixed alkali metal ozonide superoxide. The title compound crystallizes in the trigonal space group P3121 (No.152) with a = 929.02(3) and c = 1028.63(8) pm and three formula units per unit cell. The cesium cations, O3 and O2 together build a honeycomb-like framework structure with channels extending along [001]. The channels are occupied by ammonia molecules.