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Journal Article

Intramolecular Aryl-Aryl Coupling of Fluoroarenes through Al2O3-Mediated HF Elimination

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Amsharov,  K. Y.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;
Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Amsharov, K. Y., & Merz, P. (2012). Intramolecular Aryl-Aryl Coupling of Fluoroarenes through Al2O3-Mediated HF Elimination. Journal of Organic Chemistry, 77(12), 5445-5448.


Cite as: https://hdl.handle.net/21.11116/0000-000E-C2EA-F
Abstract
A strategy for effective intramolecular aryl-aryl coupling of fluoroarenes through Al2O3-mediated HF elimination is reported. It is demonstrated that the C-F bond, which is widely believed to be the most passive functionality in organic chemistry, can be reconsidered as a useful functional group allowing very effective C-C bond formation. The solid-state strategy presented in this study opens the possibility for facile syntheses of insoluble extended polycyclic aromatic hydrocarbons.