On the Rare Earth Metal Bismuthide Oxides RE2BiO2 (RE = Nd, Tb, Dy, Ho)

Nuss, J.; Jansen, M.

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On the Rare Earth Metal Bismuthide Oxides RE₂BiO₂ (RE = Nd, Tb, Dy, Ho)

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Nuss, J.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;
Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen, M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Nuss, J., & Jansen, M. (2012). On the Rare Earth Metal Bismuthide Oxides RE₂BiO₂ (RE = Nd, Tb, Dy, Ho). Zeitschrift für anorganische und allgemeine Chemie, 638(3-4), 611-613.

Cite as: https://hdl.handle.net/21.11116/0000-000E-C2F2-5

Abstract

A series of new RE2BiO2 compounds (RE = Nd, Tb, Dy, Ho) has been synthesized from elemental bismuth, REBi, and RE2O3 in all-solid state reactions in sealed tantalum ampoules at 1770 K. The dark grey metallic compounds adopt the anti-ThCr2Si2 type of structure (I4/mmm, tI10), according to X-ray single crystal structure analysis. As a main structural feature, there are PbO analogous slabs, [REO]+, and 44 nets of Bi2 anions, alternately stacked along the c-axis.