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Journal Article

In Situ Synthesis of Chlorinated Fullerenes by the High-Frequency Furnace Method

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Müller,  A.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Ziegler,  K.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Amsharov,  K. Y.
Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society;
Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Müller, A., Ziegler, K., Amsharov, K. Y., & Jansen, M. (2011). In Situ Synthesis of Chlorinated Fullerenes by the High-Frequency Furnace Method. European Journal of Inorganic Chemistry, 2011(2), 268-272.


Cite as: https://hdl.handle.net/21.11116/0000-000E-C0A9-A
Abstract
Exohedrally chlorinated fullerenes have been synthesized by in situ chlorination using the high-frequency furnace method in the presence of carbon tetrachloride as reagent. In addition to the previously reported chlorinated non-IPR (isolated pentagon rule) fullerene cages of C(2n)Cl(2m) (n = 25, 27, 28, 30, 32 and 33, m = 2-6), a C(68) and various new higher fullerenes including C(2n)Cl(2m) with n = 36, 37 and 39 were present in the soot extracts in significant quantities, as shown by HPLC/off-line mass spectrometric analyses. A more detailed analysis showed the presence of several species with the same carbon content that could arise from either the formation of different isomers or different degrees of chlorination.