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Journal Article

Supramolecular Intercluster Compounds Consisting of 1D Arrays of Silver Alkynyl Clusters and Wells-Dawson Anions, Displaying Ligand-Free Interfaces

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Gruber, F., & Jansen, M. (2011). Supramolecular Intercluster Compounds Consisting of 1D Arrays of Silver Alkynyl Clusters and Wells-Dawson Anions, Displaying Ligand-Free Interfaces. Zeitschrift für anorganische und allgemeine Chemie, 637(12 Sp. Iss. SI), 1676-1679.


Cite as: https://hdl.handle.net/21.11116/0000-000E-BFB5-F
Abstract
Combining polymeric silver alkynyl clusters with the Wells-Dawson polyoxometalate [P(2)W(18)O(62)](6) has led to the formation of the first chain-like intercluster compounds {[Ag(14)(C=CtBu)(8)(C(3)H(7)NO)(10)]-[Ag(12)(C=CtBu)(6)Cl(C(3)H(7)NO)(10 )]H[P(2)W(18)O(62)](2)}(n) (1) and {[Ag(16)-C=CtBu)(11)(CH(3)CN)(6)][P(2)W(18)O(62)]}(2)[Ag(14)(C=CtBu)(12) (CH(3)CN)(2)] (2). Both compounds contain large, yet-unknown silver alkynyl clusters as cationic building blocks which are linked to the polyanions by direct silver-oxygen contacts, i.e. by ligand-free interfaces.