Sustained Lithium-Storage Performance of Hierarchical, Nanoporous Anatase TiO2 
at High Rates: Emphasis on Interfacial Storage Phenomena

Shin, J. Y.; Samuelis, D.; Maier, J.

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Sustained Lithium-Storage Performance of Hierarchical, Nanoporous Anatase TiO₂ at High Rates: Emphasis on Interfacial Storage Phenomena

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Maier, J.
Department Physical Chemistry of Solids (Joachim Maier), Max Planck Institute for Solid State Research, Max Planck Society;

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Shin, J. Y., Samuelis, D., & Maier, J. (2011). Sustained Lithium-Storage Performance of Hierarchical, Nanoporous Anatase TiO₂ at High Rates: Emphasis on Interfacial Storage Phenomena. Advanced Functional Materials, 21(18), 3464-3472.

Cite as: https://hdl.handle.net/21.11116/0000-000E-BFB9-B

Abstract

A hierarchical, nanoporous TiO(2) structure is successfully prepared by a simple in situ hydrolysis method. Used as an anode material, it achieves a sustained high lithium storage performance especially at high charge/discharge rates due to its substantially high surface area. The material shows two different major storage modes: a) bulk insertion, and b) pseudo-capacitive interfacial storage, which is responsible for 64% of the total capacity. In order to kinetically emphasize the interfacial storage even further, we cycle the material directly at high rates, giving 302 mA h g(-1) and 200 mA h g(-1) of fully reversible discharge capacity at charge/discharge rates of 1 C and 5 C with very high cycle stability. We propose an overall view on the different Li insertion mechanisms of the high-surface-area nanoporous TiO(2) and emphasize the importance of interfacial storage for electrode applications in Li-ion batteries.