Experimental evidence for the coexistence of order/disorder and displacive 
behavior of hydrogen-bonded ferroelectrics and antiferroelectrics

Dalal, N. S.; Gunaydin-Sen, O.; Bussmann-Holder, A.

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Experimental evidence for the coexistence of order/disorder and displacive behavior of hydrogen-bonded ferroelectrics and antiferroelectrics

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Bussmann-Holder, A.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;
Department Electronic Structure Theory (Ali Alavi), Max Planck Institute for Solid State Research, Max Planck Society;
Department Physical Chemistry of Solids (Joachim Maier), Max Planck Institute for Solid State Research, Max Planck Society;
Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Dalal, N. S., Gunaydin-Sen, O., & Bussmann-Holder, A. (2007). Experimental evidence for the coexistence of order/disorder and displacive behavior of hydrogen-bonded ferroelectrics and antiferroelectrics. In Ferro- and Antiferroelectricity: Order/Disorder versus Displacive (pp. 23-50). Berlin/Heidelberg, Germany: Springer Verlag.

Cite as: https://hdl.handle.net/21.11116/0000-000E-B6E7-0

Abstract

This chapter describes the experimental complement of theoretical models of the microscopic mechanism of ferroelectric transitions. We use the hydrogen-bonded compounds as examples, and attempt to show that the new experimental data obtained via recently developed high resolution nuclear magnetic resonance techniques for solids clearly support the hypothesis that the transition mechanism must involve lattice polarizability (i.e. a displacive component), in addition to the order/disorder behaviour of the lattices.