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Order and disorder in cluster phases – The case of La≈0.7(Al≈0.1I≈0.9)

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Kienle,  L.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;
Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society;

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Oeckler,  O.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Duppel,  V.
Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society;
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Mattausch,  Hj.
Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society;
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Simon,  A.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Kienle, L., Oeckler, O., Weber, T., Duppel, V., Mattausch, H., & Simon, A. (2007). Order and disorder in cluster phases – The case of La≈0.7(Al≈0.1I≈0.9). European Journal of Inorganic Chemistry, 2007(13), 1897-1902.


Cite as: https://hdl.handle.net/21.11116/0000-000E-B7F9-B
Abstract
The structure of the new partially ordered cluster phase La-0.69(1)(Al0.12(1)I0.88(1)) was determined by a combined methodical approach of electron microscopy techniques and X-ray diffraction. The structure is derived from the Gd3CCl3-type and ca. 50% of the cluster positions in this structure type are occupied. The majority of the clusters are condensed via common edges, however, the degree of cluster condensation is low. The arrangement of neighboring clusters is comparable to chemically related, but strongly disordered cluster phases. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).