English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Raman spectroelectrochemistry on SWNTs at higher doping levels: Evidence for a transition to intercalative doping

MPS-Authors
/persons/resource/persons279885

Dettlaf-Weglikowska,  U.
Abteilung v. Klitzing, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280070

Hornbostel,  B.
Abteilung v. Klitzing, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280443

Roth,  S.
Abteilung v. Klitzing, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Rafailov, P. M., Thomsen, C., Dettlaf-Weglikowska, U., Hornbostel, B., & Roth, S. (2007). Raman spectroelectrochemistry on SWNTs at higher doping levels: Evidence for a transition to intercalative doping. physica status solidi (b), 244(11), 4060-4063.


Cite as: https://hdl.handle.net/21.11116/0000-000E-B7B9-3
Abstract
We studied the transition from the electrochemical double-layer charging regime to intercalative doping of SWNT buckypaper in KC1 aqueous solution. For this purpose we used doping levels by applying constant potentials above 1 V approaching and slightly exceeding the oxidation potential for Cl- ions. At each potential in situ Raman measurements of the radial breathing mode (RBM), the high-energy tangential mode (HEM) and the disorder-induced (D) mode were performed. From a comparative analysis of the Raman spectra we conclude that above I V a significant penetration of chlorine species into the interstitial channels of the SANT bundles and possibly functionalization take place. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.