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Journal Article

Synthesis and crystal structure of K6Mo10O33

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Arumugam,  N.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Peters,  E. M.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Arumugam, N., Peters, E. M., & Jansen, M. (2007). Synthesis and crystal structure of K6Mo10O33. Zeitschrift für Naturforschung B, 62(1), 1-4.


Cite as: https://hdl.handle.net/21.11116/0000-000E-B4D3-8
Abstract
A new potassium molybdenum oxide, K6MoO10O33, was synthesized by solid state reaction from the appropriate quantities of pre-dried MoO3 and K2MoO4, fired at around 650 degrees C for 2 d. The structure has been solved by using single crystal X-ray diffraction. The compound adopts the space group P1, with the lattice constants a=7.7100(5), b=11.9659(8), c=17.1321(12) angstrom, alpha=86.42 (10), beta=77.18(10), gamma=74.14(10)degrees. The structure is built up of infinite chains of edge-sharing MoO6 octahedra and groups of four MoO6 octahedra forming Mo4O17 units. These sub-units are connected together by common vertices.