The highest D value for a MnII ion: Investigation of a Manganese(II) 
polyoxometalate complex by high-field electron paramagnetic resonance

Pichon, C.; Mialane, P.; Rivière, E.; Blain, G.; Dolbecq, A.; Marrot, J.; Sécheresse, F.; Duboc, C.

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The highest D value for a Mn^II ion: Investigation of a Manganese(II) polyoxometalate complex by high-field electron paramagnetic resonance

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Duboc, C.
High Magnetic Field Laboratory, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Pichon, C., Mialane, P., Rivière, E., Blain, G., Dolbecq, A., Marrot, J., et al. (2007). The highest D value for a Mn^II ion: Investigation of a Manganese(II) polyoxometalate complex by high-field electron paramagnetic resonance. Inorganic Chemistry, 46(19), 7710-7712.

Cite as: https://hdl.handle.net/21.11116/0000-000E-B429-9

Abstract

Using magnetization measurements and multifrequency high-field electron paramagnetic resonance, the largest zero-field splitting for any individual isolated Mn-II ion has been found in a polyoxometalate complex, suggesting that the inorganic ligand induces large Ising-type magnetic anisotropy.