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CsMn2P2, a manganese(II, III) phosphide with BaZn2P2 structure. With a contribution to the BaAl4 structure type

MPS-Authors
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von Schnering,  H. G.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Hönle,  W.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280382

Peters,  K.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

/persons/resource/persons280381

Peters,  E.-M.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Kremer,  R. K.
Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society;

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Chang,  J.-H.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

von Schnering, H. G., Türck, R., Hönle, W., Peters, K., Peters, E.-M., Kremer, R. K., et al. (2002). CsMn2P2, a manganese(II, III) phosphide with BaZn2P2 structure. With a contribution to the BaAl4 structure type. Zeitschrift für anorganische und allgemeine Chemie, 628(12), 2772-2777.


Cite as: https://hdl.handle.net/21.11116/0000-000E-AE69-9
Abstract
CsMn2P2 is formed by the reaction of Cs4P6 with Mn and red phosphorus (Nb ampoule; 1073 K) as black platelets. The compound is paramagnetic following the Curie-Weiss law above 110 K (mu = 4.81 B.M. / CsMn2P2; theta = -79 K) and orders antiferromagnetically below 110 K. The magnetic moment corresponds with the ratio Mn-II : Mn-III = 1:1. CsMn2P2 is isotypic with BaZn2P2 (tI10; I4/mmm; a = 4.098(1) Angstrom, c = 14.215(4)Angstrom, d(Mn-P) = 2.387(1)Angstrom (4x), d(Cs-P) = 3.718(2)Angstrom (8x)), and shows, therefore, no P-P-bonds. The different regions of the BaAl4 (ThCr2Si2) structure type are analysed and parameterized once more.