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Journal Article

A multifunctional three-fold interpenetrated coordination polymer showing excellent luminescent sensing for Cr(VI)/ Fe(III) and photocatalytic properties

MPS-Authors

Bi,  Shuang-yu
Max Planck Institute for Terrestrial Microbiology, Max Planck Society;

External Resource

https://doi.org/10.1016/j.jssc.2017.09.005
(Publisher version)

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Citation

Zhu, Z., Wang, M., Xu, C.-g., Zong, Z.-a., Zhang, D.-m., Bi, S.-y., et al. (2017). A multifunctional three-fold interpenetrated coordination polymer showing excellent luminescent sensing for Cr(VI)/ Fe(III) and photocatalytic properties. JOURNAL OF SOLID STATE CHEMISTRY, 256, 176-183. doi:10.1016/j.jssc.2017.09.005.


Cite as: https://hdl.handle.net/21.11116/0000-000E-0CA0-0
Abstract
A three-fold interpenetrated coordination polymer [Cd-2(L)(bibp)(3)](n)
(1) (114L = 5,5'-(1,4-phenylenebis(methoxy))diisophthalic acid, bibp =
4,4'-bis(imidazolyl)biphenyl) has been rationally constructed,
successfully solvothermally synthesized and fully characterized. Complex
1 shows a 3D three-fold interpenetrated novel topological framework with
the point symbol (4. 6(9))2(4(2). 6(2). 7. 8), and represents a variety
of potential applications. Luminescence studies demonstrate that 1 has
high selectivity and sensitivity for pollutant Cr(VI) (CrO42- and
Cr2O72-) anion and Fe(III) cation; Photocatalytic studies show that 1
exhibits great degradation activity of three organic dyes (methylene
blue (MB), Rhodamine B (RhB) and MalachiteGreen oxalate (MGO)).
Furthermore, the possible mechanisms of the luminescent quench and
photocatalytic properties have been deduced.