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Reactions of 2-lithio- and 2-titano-methyl-quinoline reagents: the necessity of using an excess of titanating agents in adjusting molecular recognition

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Citation

Reetz, M. T., & Wünsch, T. (1990). Reactions of 2-lithio- and 2-titano-methyl-quinoline reagents: the necessity of using an excess of titanating agents in adjusting molecular recognition. Journal of the Chemical Society, Chemical Communications, 1990(22), 1562-1564. doi:10.1039/C39900001562.


Cite as: https://hdl.handle.net/21.11116/0000-000E-7CCF-F
Abstract
The extremely reactive and unselective 2-lithiomethyl-quinoline 1 can be titanated with an excess of Ti(OPri)4 or ClTi(OPri)3 to produce titanium analogues which react chemoselectively with carbonyl compounds.